Poly[[diaquabis(μ3-maleato-κ4 O 1:O 1′,O 4:O4′)dicopper(II)] trihydrate]
نویسندگان
چکیده
In the title compound, {[Cu(2)(C(4)H(2)O(4))(2)(H(2)O)(2)]·3H(2)O}(n), Cu(II) ions with square-pyramidal coordination are bridged by exo-tri-dentate maleate dianions into [Cu(2)(maleate)(2)(H(2)O)(2)](n) layers coincident with the bc crystal plane. The inter-lamellar regions contain hydrogen-bonded cyclic water hexa-mers which facilitate layer stacking into a pseudo-three-dimensional crystal structure. The water hexamers themselves are formed by the operation of crystallographic inversion centers on sets of three crystallographically distinct water molecules of hydration.
منابع مشابه
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